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Beilstein J. Org. Chem. 2022, 18, 935–943, doi:10.3762/bjoc.18.93
Graphical Abstract
Scheme 1: Reuben G. Jones synthesis of 2-hydroxypyrazines.
Scheme 2: Four hypothetical reaction intermediates.
Figure 1: ORTEP depiction of compound 4{1,2}.
Scheme 3: Suggested mechanism for the Reuben G. Jones synthesis of 2-hydroxypyrazines.
Scheme 4: Tetraethylammonium hydroxide-mediated condensation of glyoxal (1{3}), methylglyoxal (1{4}), or 2-(4...